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We report on the characterization of various salts of [Mn III 6 Cr III ] 3+ complexes prepared on substrates such as highly oriented pyrolytic graphite (HOPG), mica, SiO2, and Si3N4. [Mn III 6 Cr III ] 3+ is a single-molecule magnet, i.e., a superparamagnetic molecule, with a blocking temperature around 2 K. The three positive charges of [Mn III 6 Cr III ] 3+ were electrically neutralized by ...read more


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6/19/2017 · Characterisation of 1 and 2 included a single‐crystal X‐ray crystallographic study (Scheme 2b for 2, supporting materials for 1), and complex 2 is the first structurally characterised example of an F 3 C 6 H 3 ‐transition metal complex. Significant disorder of the fluoroarene ring between different rotomers means that discussion of the ...read more


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